Repository logo
 

Microscopy of Diffuse Nematic-Isotropic Transition in Main-Chain Nematic Liquid-Crystal Elastomers

Accepted version
Peer-reviewed

Type

Article

Change log

Authors

Abstract

Nematic-isotropic phase transition in liquid crystal elastomers (LCE), which drastically alters the macroscopic properties of the material, is attractive for both fundamental physics and applications. Here, we introduce new experimental methods based on polarized and fluorescence optical microscopy to characterize the phase transition of polydomain LCE, monitoring the order parameter and the nematic domain structure. It is demonstrated that polydomain main-chain nematic LCE exhibit an ordering transition very different from the classical first-order one, having a diffuse continuous nature. Unexpectedly, characteristic correlation length of the fading polydomain structure remains unchanged across the transition.

Description

Keywords

40 Engineering, 34 Chemical Sciences

Journal Title

Macromolecules

Conference Name

Journal ISSN

0024-9297
1520-5835

Volume Title

54

Publisher

American Chemical Society (ACS)

Rights

All rights reserved
Sponsorship
European Research Council (786659)
ERC H2020