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dc.contributor.authorCole, Jacquien
dc.contributor.authorGosztola, David Jen
dc.contributor.authorVelazquez-Garcia, Jose de Jen
dc.date.accessioned2021-04-19T23:31:24Z
dc.date.available2021-04-19T23:31:24Z
dc.date.issued2021-04-19en
dc.identifier.issn1932-7447
dc.identifier.urihttps://www.repository.cam.ac.uk/handle/1810/321304
dc.description.abstractMaterials that exhibit nanooptomechanical transduction in their single-crystal form have prospective use in light-driven molecular machinery, nanotechnology and quantum computing. Linkage photoisomerization is typically the source of such transduction in coordination complexes, although the isomers tend to undergo only partial photoconver- sion. We present a nanooptomechanical transducer, trans-[Ru(SO2)(NH3)4(3-bromopyridine)]tosylate2, whose S-bound 1-SO2 isomer fully converts into an O-bound 1-OSO photoisomer that is metastable while kept at 100 K. Its 100% photo- conversion is confirmed structurally via photocrystallography, while single-crystal optical absorption and Raman spec- troscopies reveal its metal-to-ligand charge-transfer and temperature-dependent characteristics. This perfect optical switching affords the material good prospects for nanooptomechanical transduction with single-photon control.
dc.description.sponsorshipBASF/Royal Academy of Engineering Research Chair STFC The 1851 Royal Commission of the Great Exhibition U.S. Department of Energy (DOE) Office of Science, Office of Basic Energy Sciences (contract no. DE- AC02-06CH11357) The National Council of Science and Technology of Mexico (CONACyT) Cambridge Trust (Ph.D. scholarship 217553).
dc.format.mediumPrint-Electronicen
dc.languageengen
dc.rightsAll rights reserved
dc.rights.uri
dc.titleNanooptomechanical Transduction in a Single Crystal with 100% Photoconversion.en
dc.typeArticle
prism.endingPage8915
prism.issueIdentifier16en
prism.publicationDate2021en
prism.publicationNameThe journal of physical chemistry. C, Nanomaterials and interfacesen
prism.startingPage8907
prism.volume125en
dc.identifier.doi10.17863/CAM.68428
dcterms.dateAccepted2021-04-15en
rioxxterms.versionofrecord10.1021/acs.jpcc.1c02457en
rioxxterms.versionAM
rioxxterms.licenseref.urihttp://www.rioxx.net/licenses/all-rights-reserveden
rioxxterms.licenseref.startdate2021-04-19en
dc.contributor.orcidCole, Jacqueline [0000-0002-1552-8743]
dc.contributor.orcidGosztola, David J [0000-0003-2674-1379]
dc.identifier.eissn1932-7455
rioxxterms.typeJournal Article/Reviewen
pubs.funder-project-idRoyal Academy of Engineering (RAEng) (RCSRF1819\7\10)
pubs.funder-project-idSTFC (Unknown)
pubs.funder-project-idSTFC (Unknown)
cam.orpheus.successMon Apr 26 07:30:30 BST 2021 - Embargo updated*
rioxxterms.freetoread.startdate2022-04-19


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