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The Role of Dimensionality on the Optoelectronic Properties of Oxide and Halide Perovskites, and their Halide Derivatives

Published version
Peer-reviewed

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Abstract

jats:titleAbstract</jats:title>jats:pHalide perovskite semiconductors have risen to prominence in photovoltaics and light‐emitting diodes (LEDs), but traditional oxide perovskites, which overcome the stability limitations of their halide counterparts, have also recently witnessed a rise in potential as solar absorbers. One of the many important factors underpinning these developments is an understanding of the role of dimensionality on the optoelectronic properties and, consequently, on the performance of the materials in photovoltaics and LEDs. This review article examines the role of structural and electronic dimensionality, as well as form factor, in oxide and halide perovskites, and in lead‐free alternatives to halide perovskites. Insights into how dimensionality influences the band gap, stability, charge‐carrier transport, recombination processes and defect tolerance of the materials, and the impact these parameters have on device performance are brought forward. Particular emphasis is placed on carrier/exciton‐phonon coupling, which plays a significant role in the materials considered, owing to their soft lattices and composition of heavy elements, and becomes more prominent as dimensionality is reduced. It is finished with a discussion of the implications on the classes of materials future efforts should focus on, as well as the key questions that need to be addressed.</jats:p>

Description

Funder: Kim and Juliana Silverman Research Fellowship


Funder: Graduate Assistance in Areas of National Need

Keywords

defects, electronic dimensionality, light&#8208, emitting diodes, perovskite&#8208, inspired materials, perovskites, photovoltaics, structural dimensionality

Journal Title

Advanced Energy Materials

Conference Name

Journal ISSN

1614-6832
1614-6840

Volume Title

Publisher

Wiley
Sponsorship
Engineering and Physical Sciences Research Council (EP/N509620/1)
Engineering and Physical Sciences Research Council (EP/P007767/1)
European Commission Horizon 2020 (H2020) ERC (882929)