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dc.contributor.authorBelenguer, Ana
dc.contributor.authorMichalchuk, Adam AL
dc.contributor.authorLampronti, Giulio I
dc.contributor.authorSanders, Jeremy
dc.date.accessioned2021-12-23T00:30:25Z
dc.date.available2021-12-23T00:30:25Z
dc.date.issued2022-02-08
dc.identifier.issn1864-5631
dc.identifier.urihttps://www.repository.cam.ac.uk/handle/1810/331730
dc.description.abstractIt was shown for the first time that solid amines can act as catalysts for disulfide-based dynamic combinatorial chemistry (DCC) by ball mill grinding. The mechanochemical equilibrium for the two disulfide reactions studied was reached within 1-3 h using ten different amine catalysts. This contrasts with the weeks to months to achieve solution equilibrium for most solid amine catalysts at 2 %mol mol-1 concentration in a 2 mMolar disulfide dynamic combinatorial library in a suitable solvent. The final mechanochemical equilibrium was independent of the catalyst used but varied with other ball mill grinding factors such as the presence of traces of solvent. The different efficiencies of the amines tested were discussed.
dc.publisherWiley
dc.rightsAll Rights Reserved
dc.rights.urihttp://www.rioxx.net/licenses/all-rights-reserved
dc.titleUsing Solid Catalysts in Disulfide-Based Dynamic Combinatorial Solution- and Mechanochemistry.
dc.typeArticle
dc.publisher.departmentDepartment of Chemistry
dc.date.updated2021-12-07T13:53:10Z
prism.publicationNameChemSusChem
dc.identifier.doi10.17863/CAM.79179
dcterms.dateAccepted2021-12-03
rioxxterms.versionofrecord10.1002/cssc.202102416
rioxxterms.versionAM
dc.contributor.orcidBelenguer, Ana [0000-0002-0443-4856]
dc.contributor.orcidMichalchuk, Adam AL [0000-0001-7405-3269]
dc.contributor.orcidLampronti, Giulio I [0000-0002-1430-3446]
dc.contributor.orcidSanders, Jeremy [0000-0002-5143-5210]
dc.identifier.eissn1864-564X
rioxxterms.typeJournal Article/Review
cam.issuedOnline2021-12-23
cam.orpheus.success2021-12-22 - Embargo set during processing via Fast-track
cam.depositDate2021-12-07
pubs.licence-identifierapollo-deposit-licence-2-1
pubs.licence-display-nameApollo Repository Deposit Licence Agreement
rioxxterms.freetoread.startdate2022-12-04


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