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dc.contributor.authorGreaney, Michael F
dc.contributor.authorWhalley, David
dc.date.accessioned2021-12-24T00:31:02Z
dc.date.available2021-12-24T00:31:02Z
dc.date.issued2022-04
dc.identifier.issn0039-7881
dc.identifier.urihttps://www.repository.cam.ac.uk/handle/1810/331765
dc.description.abstract<jats:title>Abstract</jats:title><jats:p>The Smiles rearrangement has undergone a renaissance in recent years providing new avenues for non-canonical arylation techniques in both the radical and polar regimes. This short review will discuss recent applications of the reaction (from 2017 to late 2021), including its relevance to areas such as heterocycle synthesis and the functionalization of alkenes and alkynes as well as glimpses at new directions for the field.</jats:p><jats:p>1 Introduction</jats:p><jats:p>2 Polar Smiles Rearrangements</jats:p><jats:p>3 Radical Smiles: Alkene and Alkyne Functionalization</jats:p><jats:p>4 Radical Smiles: Rearrangements via C–X Bond Cleavage</jats:p><jats:p>5 Radical Smiles: Miscellaneous Rearrangements</jats:p><jats:p>6 Conclusions</jats:p>
dc.publisherGeorg Thieme Verlag KG
dc.rightsAll Rights Reserved
dc.rights.urihttp://www.rioxx.net/licenses/all-rights-reserved
dc.titleRecent Advances in the Smiles Rearrangement: New Opportunities for Arylation
dc.typeArticle
dc.publisher.departmentDepartment of Chemistry
dc.date.updated2021-12-22T10:23:11Z
prism.publicationDate2021
prism.publicationNameSynthesis
dc.identifier.doi10.17863/CAM.79214
rioxxterms.versionofrecord10.1055/a-1710-6289
rioxxterms.versionAM
dc.contributor.orcidWhalley, David [0000-0002-5988-7457]
dc.identifier.eissn1437-210X
rioxxterms.typeJournal Article/Review
cam.issuedOnline2021-12-01
cam.orpheus.success2021-12-23 - Embargo set during processing via Fast-track
cam.depositDate2021-12-22
pubs.licence-identifierapollo-deposit-licence-2-1
pubs.licence-display-nameApollo Repository Deposit Licence Agreement
rioxxterms.freetoread.startdate2022-12-01


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