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dc.contributor.authorZhang, Dawei
dc.contributor.authorGan, Quan
dc.contributor.authorPlajer, Alex J
dc.contributor.authorLavendomme, Roy
dc.contributor.authorRonson, Tanya
dc.contributor.authorLu, Zifei
dc.contributor.authorJensen, Jesper D
dc.contributor.authorLaursen, Bo W
dc.contributor.authorNitschke, Jonathan
dc.date.accessioned2022-01-11T00:30:20Z
dc.date.available2022-01-11T00:30:20Z
dc.date.issued2022-01-26
dc.identifier.issn0002-7863
dc.identifier.urihttps://www.repository.cam.ac.uk/handle/1810/332582
dc.description.abstractWe report the construction of three structurally distinct self-assembled architectures: FeII12L12 pseudoicosahedron 1, FeII2L3 helicate 2, and FeII4L4 tetrahedron 3, formed from a single triazatriangulenium subcomponent A under different reaction conditions. Pseudoicosahedral capsule 1 is the largest formed through subcomponent self-assembly to date, with an outer-sphere diameter of 5.4 nm and a cavity volume of 15 nm3. The outcome of self-assembly depended upon concentration, where the formation of pseudoicosahedron 1 was favored at higher concentrations, while helicate 2 exclusively formed at lower concentrations. The conversion of pseudoicosahedron 1 or helicate 2 into tetrahedron 3 occurred following the addition of a CB11H12- or B12F122- template.
dc.description.sponsorshipUK Engineering and Physical Sciences Research Council (EPSRC EP/P027067/1)
dc.publisherAmerican Chemical Society (ACS)
dc.rightsAll Rights Reserved
dc.rights.urihttp://www.rioxx.net/licenses/all-rights-reserved
dc.titleTemplation and Concentration Drive Conversion Between a FeII12L12 Pseudoicosahedron, a FeII4L4 Tetrahedron, and a FeII2L3 Helicate.
dc.typeArticle
dc.publisher.departmentDepartment of Chemistry
dc.date.updated2022-01-05T13:24:06Z
prism.publicationNameJ Am Chem Soc
dc.identifier.doi10.17863/CAM.79755
dcterms.dateAccepted2022-01-04
rioxxterms.versionofrecord10.1021/jacs.1c11536
rioxxterms.versionAM
dc.contributor.orcidZhang, Dawei [0000-0002-0898-9795]
dc.contributor.orcidGan, Quan [0000-0003-4612-2268]
dc.contributor.orcidLavendomme, Roy [0000-0001-6238-8491]
dc.contributor.orcidRonson, Tanya [0000-0002-6917-3685]
dc.contributor.orcidLaursen, Bo W [0000-0002-1120-3191]
dc.contributor.orcidNitschke, Jonathan [0000-0002-4060-5122]
dc.identifier.eissn1520-5126
rioxxterms.typeJournal Article/Review
pubs.funder-project-idEuropean Research Council (695009)
pubs.funder-project-idEngineering and Physical Sciences Research Council (EP/P027067/1)
cam.issuedOnline2022-01-11
cam.orpheus.successTue Feb 01 19:02:37 GMT 2022 - Embargo updated
cam.depositDate2022-01-05
pubs.licence-identifierapollo-deposit-licence-2-1
pubs.licence-display-nameApollo Repository Deposit Licence Agreement
rioxxterms.freetoread.startdate2023-01-11


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