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dc.contributor.authorBumstead, Alice M
dc.contributor.authorPakamorė, Ignas
dc.contributor.authorRichards, Kieran D
dc.contributor.authorThorne, Michael F
dc.contributor.authorBoyadjieva, Sophia S
dc.contributor.authorCastillo-Blas, Celia
dc.contributor.authorMcHugh, Lauren N
dc.contributor.authorSapnik, Adam F
dc.contributor.authorKeeble, Dean S
dc.contributor.authorKeen, David A
dc.contributor.authorEvans, Rachel
dc.contributor.authorForgan, Ross S
dc.contributor.authorBennett, Thomas
dc.date.accessioned2022-02-09T00:31:02Z
dc.date.available2022-02-09T00:31:02Z
dc.date.issued2022-03-08
dc.identifier.issn0897-4756
dc.identifier.urihttps://www.repository.cam.ac.uk/handle/1810/333765
dc.description.abstractMelt-quenched metal-organic framework (MOF) glasses have gained significant interest as the first new category of glass reported in 50 years. In this work, an amine-functionalized zeolitic imidazolate framework (ZIF), denoted ZIF-UC-6, was prepared and demonstrated to undergo both melting and glass formation. The presence of an amine group resulted in a lower melting temperature compared to other ZIFs, while also allowing material properties to be tuned by post-synthetic modification (PSM). As a prototypical example, the ZIF glass surface was functionalized with octyl isocyanate, changing its behavior from hydrophilic to hydrophobic. PSM therefore provides a promising strategy for tuning the surface properties of MOF glasses.
dc.publisherAmerican Chemical Society (ACS)
dc.rightsAll Rights Reserved
dc.rights.urihttp://www.rioxx.net/licenses/all-rights-reserved
dc.titlePost-Synthetic Modification of a Metal-Organic Framework Glass.
dc.typeArticle
dc.publisher.departmentDepartment of Materials Science And Metallurgy
dc.date.updated2022-02-08T10:44:37Z
prism.publicationNameChem Mater
dc.identifier.doi10.17863/CAM.81182
dcterms.dateAccepted2022-02-04
rioxxterms.versionofrecord10.1021/acs.chemmater.1c03820
rioxxterms.versionAM
dc.contributor.orcidBumstead, Alice M [0000-0001-9269-1731]
dc.contributor.orcidEvans, Rachel [0000-0003-2956-4857]
dc.contributor.orcidForgan, Ross S [0000-0003-4767-6852]
dc.contributor.orcidBennett, Thomas [0000-0003-3717-3119]
dc.identifier.eissn1520-5002
rioxxterms.typeJournal Article/Review
pubs.funder-project-idRoyal Society (UF150021)
pubs.funder-project-idRoyal Society (RGF\EA\180092)
pubs.funder-project-idRoyal Society (RSG\R1\180395)
pubs.funder-project-idLeverhulme Trust (RPG-2020-005)
pubs.funder-project-idLeverhulme Trust (PLP-2019-002)
cam.issuedOnline2022-02-18
cam.orpheus.successWed Mar 23 10:26:29 GMT 2022 - Embargo updated
cam.orpheus.counter1
cam.depositDate2022-02-08
pubs.licence-identifierapollo-deposit-licence-2-1
pubs.licence-display-nameApollo Repository Deposit Licence Agreement
rioxxterms.freetoread.startdate2023-02-18


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