Post-Synthetic Modification of a Metal-Organic Framework Glass.
dc.contributor.author | Bumstead, Alice M | |
dc.contributor.author | Pakamorė, Ignas | |
dc.contributor.author | Richards, Kieran D | |
dc.contributor.author | Thorne, Michael F | |
dc.contributor.author | Boyadjieva, Sophia S | |
dc.contributor.author | Castillo-Blas, Celia | |
dc.contributor.author | McHugh, Lauren N | |
dc.contributor.author | Sapnik, Adam F | |
dc.contributor.author | Keeble, Dean S | |
dc.contributor.author | Keen, David A | |
dc.contributor.author | Evans, Rachel | |
dc.contributor.author | Forgan, Ross S | |
dc.contributor.author | Bennett, Thomas | |
dc.date.accessioned | 2022-02-09T00:31:02Z | |
dc.date.available | 2022-02-09T00:31:02Z | |
dc.date.issued | 2022-03-08 | |
dc.identifier.issn | 0897-4756 | |
dc.identifier.uri | https://www.repository.cam.ac.uk/handle/1810/333765 | |
dc.description.abstract | Melt-quenched metal-organic framework (MOF) glasses have gained significant interest as the first new category of glass reported in 50 years. In this work, an amine-functionalized zeolitic imidazolate framework (ZIF), denoted ZIF-UC-6, was prepared and demonstrated to undergo both melting and glass formation. The presence of an amine group resulted in a lower melting temperature compared to other ZIFs, while also allowing material properties to be tuned by post-synthetic modification (PSM). As a prototypical example, the ZIF glass surface was functionalized with octyl isocyanate, changing its behavior from hydrophilic to hydrophobic. PSM therefore provides a promising strategy for tuning the surface properties of MOF glasses. | |
dc.publisher | American Chemical Society (ACS) | |
dc.rights | All Rights Reserved | |
dc.rights.uri | http://www.rioxx.net/licenses/all-rights-reserved | |
dc.title | Post-Synthetic Modification of a Metal-Organic Framework Glass. | |
dc.type | Article | |
dc.publisher.department | Department of Materials Science And Metallurgy | |
dc.date.updated | 2022-02-08T10:44:37Z | |
prism.publicationName | Chem Mater | |
dc.identifier.doi | 10.17863/CAM.81182 | |
dcterms.dateAccepted | 2022-02-04 | |
rioxxterms.versionofrecord | 10.1021/acs.chemmater.1c03820 | |
rioxxterms.version | AM | |
dc.contributor.orcid | Bumstead, Alice M [0000-0001-9269-1731] | |
dc.contributor.orcid | Evans, Rachel [0000-0003-2956-4857] | |
dc.contributor.orcid | Forgan, Ross S [0000-0003-4767-6852] | |
dc.contributor.orcid | Bennett, Thomas [0000-0003-3717-3119] | |
dc.identifier.eissn | 1520-5002 | |
rioxxterms.type | Journal Article/Review | |
pubs.funder-project-id | Royal Society (UF150021) | |
pubs.funder-project-id | Royal Society (RGF\EA\180092) | |
pubs.funder-project-id | Royal Society (RSG\R1\180395) | |
pubs.funder-project-id | Leverhulme Trust (RPG-2020-005) | |
pubs.funder-project-id | Leverhulme Trust (PLP-2019-002) | |
cam.issuedOnline | 2022-02-18 | |
cam.orpheus.success | Wed Mar 23 10:26:29 GMT 2022 - Embargo updated | |
cam.orpheus.counter | 1 | |
cam.depositDate | 2022-02-08 | |
pubs.licence-identifier | apollo-deposit-licence-2-1 | |
pubs.licence-display-name | Apollo Repository Deposit Licence Agreement | |
rioxxterms.freetoread.startdate | 2023-02-18 |
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