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Magnetism on the stretched diamond lattice in lanthanide orthotantalates

Accepted version
Peer-reviewed

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Article

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Authors

Kelly, ND 
Yuan, L 
Pearson, RL 
Suard, E 
Puente Orench, I 

Abstract

The magnetic Ln3+ ions in the fergusonite and scheelite crystal structures form a distorted or stretched diamond lattice which is predicted to host exotic magnetic ground states. In this study, polycrystalline samples of the fergusonite orthotantalates M-LnTaO4 (Ln = Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er) are synthesized and then characterized using powder diffraction and bulk magnetometry and heat capacity. TbTaO4 orders antiferromagnetically at 2.25 K into a commensurate magnetic cell with k=0, magnetic space group 14.77 (P21/c) and Tb moments parallel to the a-axis. No magnetic order was observed in the other materials studied, leaving open the possibility of exotic magnetic states at T<2 K.

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Keywords

cond-mat.mtrl-sci, cond-mat.mtrl-sci, cond-mat.str-el

Journal Title

Physical Review Materials

Conference Name

Journal ISSN

2475-9953
2475-9953

Volume Title

Publisher

American Physical Society (APS)
Sponsorship
Engineering and Physical Sciences Research Council (EP/M000524/1)
EPSRC (EP/T028580/1)
EPSRC (2124516)
We acknowledge funding from the EPSRC (Grants No. EP/T028580/1, No. EP/R513180/1, and No. EP/M000524/1). The authors gratefully acknowledge the technical and human support provided at the Institut Laue-Langevin (ILL), Grenoble, France.
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