Show simple item record

dc.contributor.authorVijeta, Arjun
dc.contributor.authorCasadevall, Carla
dc.contributor.authorReisner, Erwin
dc.date.accessioned2022-04-13T08:00:52Z
dc.date.available2022-04-13T08:00:52Z
dc.date.issued2022-04-12
dc.date.submitted2022-02-28
dc.identifier.issn0044-8249
dc.identifier.issn1521-3757
dc.identifier.otherange202203176
dc.identifier.urihttps://www.repository.cam.ac.uk/handle/1810/336049
dc.descriptionFunder: Cambridge Trust; Id: http://dx.doi.org/10.13039/501100003343
dc.description.abstractAbstract: The synthesis of primary anilines via sustainable methods remains a challenge in organic synthesis. We report a photocatalytic protocol for the selective synthesis of primary anilines via cross‐coupling of a wide range of aryl/heteroaryl halides with sodium azide using a photocatalyst powder consisting of nickel(II) deposited on mesoporous carbon nitride (Ni‐mpg‐CN x ). This heterogeneous photocatalyst contains a high surface area with a visible light‐absorbing and adaptive “built‐in” solid‐state ligand for the integrated catalytic Ni site. The method displays a high functional group tolerance, requires mild reaction conditions, and benefits from easy recovery and reuse of the photocatalyst powder. Thereby, it overcomes the need of complex ligand scaffolds required in homogeneous catalysis, precious metals and elevated temperatures/pressures in existing protocols of primary anilines synthesis. The reported heterogeneous Ni‐mpg‐CN x holds potential for applications in the academic and industrial synthesis of anilines and exploration of other photocatalytic transformations.
dc.languageen
dc.subjectZuschrift
dc.subjectZuschriften
dc.subjectCarbon Nitride
dc.subjectGreen Chemistry
dc.subjectHeterogeneous Catalysis
dc.subjectOrganic Synthesis
dc.subjectPhotocatalysis
dc.titleAn Integrated Carbon Nitride‐Nickel Photocatalyst for the Amination of Aryl Halides Using Sodium Azide
dc.typeOther
dc.date.updated2022-04-13T08:00:52Z
prism.publicationNameAngewandte Chemie
dc.identifier.doi10.17863/CAM.83478
rioxxterms.versionofrecord10.1002/ange.202203176
rioxxterms.versionAO
rioxxterms.versionVoR
rioxxterms.licenseref.urihttp://creativecommons.org/licenses/by/4.0/
dc.contributor.orcidCasadevall, Carla [0000-0002-3090-4938]
dc.contributor.orcidReisner, Erwin [0000-0002-7781-1616]
pubs.funder-project-idEngineering and Physical Sciences Research Council (EP/S025308/1)
pubs.funder-project-idH2020 Marie Skłodowska-Curie Actions (890745)


Files in this item

Thumbnail
Thumbnail

This item appears in the following Collection(s)

Show simple item record