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Long-term solar water and CO2 splitting with photoelectrochemical BiOI-BiVO4 tandems.

Accepted version
Peer-reviewed

Type

Article

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Abstract

Photoelectrochemical (PEC) devices have been developed for direct solar fuel production but the limited stability of submerged light absorbers can hamper their commercial prospects.1,2 Here, we demonstrate photocathodes with an operational H2 evolution activity over weeks, by integrating a BiOI light absorber into a robust, oxide-based architecture with a graphite paste conductive encapsulant. In this case, the activity towards proton and CO2 reduction is mainly limited by catalyst degradation. We also introduce multiple-pixel devices as an innovative design principle for PEC systems, displaying superior photocurrents, onset biases and stability over corresponding conventional single-pixel devices. Accordingly, PEC tandem devices comprising multiple-pixel BiOI photocathodes and BiVO4 photoanodes can sustain bias-free water splitting for 240 h, while devices with a Cu92In8 alloy catalyst demonstrate unassisted syngas production from CO2.

Description

Keywords

4103 Environmental Biotechnology, 34 Chemical Sciences, 3406 Physical Chemistry, 40 Engineering, 41 Environmental Sciences, 4016 Materials Engineering

Journal Title

Nat Mater

Conference Name

Journal ISSN

1476-1122
1476-4660

Volume Title

Publisher

Springer Science and Business Media LLC
Sponsorship
European Commission Horizon 2020 (H2020) Marie Sk?odowska-Curie actions (839763)
Engineering and Physical Sciences Research Council (EP/N509620/1)
European Commission Horizon 2020 (H2020) ERC (882929)
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