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dc.contributor.authorDin Babar, Zaheer Ud
dc.contributor.authorFatheema, Jameela
dc.contributor.authorArif, Nimrah
dc.contributor.authorAnwar, Muhammad
dc.contributor.authorGul, Sundus
dc.contributor.authorIqbal, Mudassir
dc.contributor.authorRizwan, Syed
dc.date.accessioned2022-06-07T08:16:59Z
dc.date.available2022-06-07T08:16:59Z
dc.date.issued2020-07-03
dc.identifier.issn2046-2069
dc.identifier.other35518577
dc.identifier.otherPMC9055396
dc.identifier.urihttps://www.repository.cam.ac.uk/handle/1810/337843
dc.descriptionFunder: National University of Sciences and Technology
dc.description.abstractTransition metal carbides (TMCs) have recently emerged as competent members among the family of two-dimensional (2D) materials, owing to their promising applications. There are many promising applications of MXenes; however, their magnetic properties lack a wide margin, both experimentally as well as theoretically, which needs to be investigated for potential use in spintronics. In this study, we carried out a comprehensive etching process via selective extraction of Al layers from Nb2AlC-MAX using a wet electrochemical route under well-optimized conditions to obtain fine 2D-Nb2C MXene sheets. Structural analysis using X-ray diffraction (XRD) confirms the effective removal of Al followed by confirmation of a 2D layered structure from morphological analysis using scanning electron microscopy (SEM). Zero-field-cooled (ZFC) and field-cooled (FC) measurements of MAX and MXene at different field strengths were performed using a superconducting quantum interference device (SQUID). Magnetic measurements reveal the paramagnetic nature of Nb2AlC-MAX measured under 5 mT; however, this changes to a clear superconductor-like diamagnetic behavior with a shift of the magnetization from positive to negative values at low temperatures when measured under 5 mT and 10 mT for Nb2C MXene. The diamagnetism, however, is changed to paramagnetism at 100 mT, which shows the existence of critical fields known typically for a type-II superconductor. To gain an insight into this unusual behavior in MXene, density functional theory (DFT) first-principles calculation was also performed in Wein2K software using spin-polarized generalized gradient approximation (sp-GGA). The magnetic moment of the compound is calculated to be negative, which corresponds well with the experimental finding and suggests that the negative magnetic moment originated from the d-orbital of Nb2C. The present report provides a pathway to deeply understanding the existence of superconductivity-like diamagnetic behavior in Nb2C MXene, which is useful for future magnetic applications.
dc.languageeng
dc.publisherRoyal Society of Chemistry (RSC)
dc.rightsAttribution 4.0 International
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/
dc.sourcenlmid: 101581657
dc.sourceessn: 2046-2069
dc.titleMagnetic phase transition from paramagnetic in Nb2AlC-MAX to superconductivity-like diamagnetic in Nb2C-MXene: an experimental and computational analysis.
dc.typeArticle
dc.date.updated2022-06-07T08:16:59Z
prism.endingPage25678
prism.issueIdentifier43
prism.publicationNameRSC Adv
prism.startingPage25669
prism.volume10
dc.identifier.doi10.17863/CAM.85252
dcterms.dateAccepted2020-06-25
rioxxterms.versionofrecord10.1039/d0ra04568c
rioxxterms.versionVoR
rioxxterms.licenseref.urihttps://creativecommons.org/licenses/by/4.0/
dc.contributor.orcidDin Babar, Zaheer Ud [0000-0003-3293-6244]
dc.contributor.orcidArif, Nimrah [0000-0002-6978-2667]
dc.contributor.orcidAnwar, Muhammad [0000-0003-2525-3875]
dc.contributor.orcidIqbal, Mudassir [0000-0002-9830-8235]
dc.contributor.orcidRizwan, Syed [0000-0002-6934-0949]
dc.identifier.eissn2046-2069
pubs.funder-project-idUnited States Agency for International Development (783)
pubs.funder-project-idHigher Education Commission, Pakistan (6040)
cam.issuedOnline2020


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Attribution 4.0 International
Except where otherwise noted, this item's licence is described as Attribution 4.0 International