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dc.contributor.authorCarpenter, John P
dc.contributor.authorRonson, Tanya K
dc.contributor.authorRizzuto, Felix J
dc.contributor.authorHéliot, Théophile
dc.contributor.authorGrice, Peter
dc.contributor.authorNitschke, Jonathan R
dc.date.accessioned2022-06-07T08:17:03Z
dc.date.available2022-06-07T08:17:03Z
dc.date.issued2022-05-18
dc.identifier.issn0002-7863
dc.identifier.other35511929
dc.identifier.otherPMC9121369
dc.identifier.urihttps://www.repository.cam.ac.uk/handle/1810/337844
dc.descriptionFunder: University of Cambridge
dc.descriptionFunder: Cambridge Trust
dc.description.abstractBiological systems employ multimetallic assemblies to achieve a range of functions. Here we demonstrate the preparation of metal-organic cages that contain either homobimetallic or heterobimetallic vertices. These vertices are constructed using 2-formyl-6-diphenylphosphinopyridine, which forms ligands that readily bridge between a pair of metal centers, thus enforcing the formation of bimetallic coordination motifs. Two pseudo-octahedral homometallic MI12L4 cages (MI = CuI or AgI) were prepared, with a head-to-head configuration of their vertices confirmed by X-ray crystallography and multinuclear NMR for AgI. The phosphino-pyridine subcomponent also enabled the formation of a class of octanuclear CdII4CuI4L4 tetrahedral cages, representing an initial example of self-assembled cages containing well-defined heterobimetallic vertices.
dc.languageeng
dc.publisherAmerican Chemical Society (ACS)
dc.rightsAttribution 4.0 International
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/
dc.sourcenlmid: 7503056
dc.sourceessn: 1520-5126
dc.subjectMetals
dc.subjectPyridines
dc.subjectLigands
dc.subjectCrystallography, X-Ray
dc.subjectModels, Molecular
dc.titleIncorporation of a Phosphino(pyridine) Subcomponent Enables the Formation of Cages with Homobimetallic and Heterobimetallic Vertices.
dc.typeArticle
dc.date.updated2022-06-07T08:17:02Z
prism.endingPage8473
prism.issueIdentifier19
prism.publicationNameJ Am Chem Soc
prism.startingPage8467
prism.volume144
dc.identifier.doi10.17863/CAM.85253
rioxxterms.versionofrecord10.1021/jacs.2c02261
rioxxterms.versionVoR
rioxxterms.licenseref.urihttps://creativecommons.org/licenses/by/4.0/
dc.contributor.orcidRonson, Tanya K [0000-0002-6917-3685]
dc.contributor.orcidRizzuto, Felix J [0000-0003-2799-903X]
dc.contributor.orcidGrice, Peter [0000-0003-4658-4534]
dc.contributor.orcidNitschke, Jonathan R [0000-0002-4060-5122]
dc.identifier.eissn1520-5126
pubs.funder-project-idEuropean Commission (264645)
pubs.funder-project-idEuropean Research Council (695009)
pubs.funder-project-idEngineering and Physical Sciences Research Council (EP/P027067/1)
pubs.funder-project-idEPSRC (EP/T031603/1)
cam.issuedOnline2022-05-05


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Attribution 4.0 International
Except where otherwise noted, this item's licence is described as Attribution 4.0 International