Generalized thermodynamics of phase equilibria in scalar active matter.
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Authors
Solon, Alexandre P
Stenhammar, Joakim
Cates, Michael E
Kafri, Yariv
Tailleur, Julien
Abstract
Motility-induced phase separation (MIPS) arises generically in fluids of self-propelled particles when interactions lead to a kinetic slowdown at high densities. Starting from a continuum description of scalar active matter akin to a generalized Cahn-Hilliard equation, we give a general prescription for the mean densities of coexisting phases in flux-free steady states that amounts, at a hydrodynamics scale, to extremizing an effective free energy. We illustrate our approach on two well-known models: self-propelled particles interacting either through a density-dependent propulsion speed or via direct pairwise forces. Our theory accounts quantitatively for their phase diagrams, providing a unified description of MIPS.
Description
Keywords
0306 Physical Chemistry (incl. Structural)
Journal Title
Phys Rev E
Conference Name
Journal ISSN
2470-0045
2470-0053
2470-0053
Volume Title
97
Publisher
American Physical Society (APS)
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Sponsorship
Engineering and Physical Sciences Research Council (EP/J007404/1)