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Probing the interactions of dolomite surfaces with oil at the molecular scale

cam.issuedOnline2019-06-18
cam.orpheus.successThu Jan 30 10:44:13 GMT 2020 - Embargo updated
dc.contributor.authorWang, N
dc.contributor.authorCollins, IR
dc.contributor.authorWebb, KJ
dc.contributor.authorWan, Q
dc.contributor.authorDurkan, C
dc.contributor.orcidDurkan, C [0000-0001-9398-2813]
dc.date.accessioned2019-06-27T23:30:35Z
dc.date.available2019-06-27T23:30:35Z
dc.date.issued2019
dc.description.abstractThe oil wettability of reservoir rock surfaces is a key issue affecting oil production and enhanced oil recovery. Understanding of the factors that determine this wettability and how to change the rock wetting state is necessary in order to improve oil recovery efficiency. In this study, Atomic Force Microscopy (AFM) has been used to study the change of wettability of dolomites after exposure to crude oil. Oil aggregates are seen to adhere to particular areas of the surface in a manner dependent on the surface electrical potential, with a higher affinity towards regions of the surface with negative charge indicating that asphaltenes possess a native positive charge. The effect of exposure to brine has also been studied, the key finding being that via a modification of the surface potential, it leads to significantly less adsorption of the polar components of oil.
dc.identifier.doi10.17863/CAM.41198
dc.identifier.eissn1520-5029
dc.identifier.issn0887-0624
dc.identifier.urihttps://www.repository.cam.ac.uk/handle/1810/294097
dc.language.isoeng
dc.publisherAmerican Chemical Society (ACS)
dc.publisher.urlhttp://dx.doi.org/10.1021/acs.energyfuels.9b00972
dc.rightsAll rights reserved
dc.subject40 Engineering
dc.subject4019 Resources Engineering and Extractive Metallurgy
dc.titleProbing the interactions of dolomite surfaces with oil at the molecular scale
dc.typeArticle
dcterms.dateAccepted2019-06-18
prism.endingPage6169
prism.issueIdentifier7
prism.publicationDate2019
prism.publicationNameEnergy and Fuels
prism.startingPage6161
prism.volume33
rioxxterms.licenseref.startdate2019-07-18
rioxxterms.licenseref.urihttp://www.rioxx.net/licenses/all-rights-reserved
rioxxterms.typeJournal Article/Review
rioxxterms.versionAM
rioxxterms.versionofrecord10.1021/acs.energyfuels.9b00972

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