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Re-imagining the daniell cell: ampere-hour-level rechargeable Zn-Cu batteries.

Accepted version
Peer-reviewed

Type

Article

Change log

Authors

Guo, Jiawei 
Xiong, Fangyu 
Yang, Yixu 

Abstract

The Daniell cell (Cu vs. Zn), was invented almost two centuries ago, but has been set aside due to its non-rechargeable nature and limited energy density. However, these cells are exceptionally sustainable because they do not require rare earth elements, are aqueous and easy to recycle. This work addresses key challenges in making Daniell cells relevant to our current energy crisis. First, we propose new approaches to stabilise Zn and Cu plating and stripping processes and create a rechargeable cell. Second, we replace salt bridges with an anion exchange membrane, or a bipolar membrane for alkaline-acid hybrid Zn-Cu batteries operating at 1.56 V. Finally, we apply these changes in pouch cells in order to increase energy and power density. These combined developments result in a rechargeable Daniell cell, which can achieve high areal capacities of 5 mA h cm-2 and can easily be implemented in 1 A h pouch cells.

Description

Keywords

40 Engineering, 34 Chemical Sciences, 3406 Physical Chemistry, 7 Affordable and Clean Energy

Journal Title

Energy Environ Sci

Conference Name

Journal ISSN

1754-5692
1754-5706

Volume Title

Publisher

Royal Society of Chemistry
Sponsorship
European Commission Horizon 2020 (H2020) ERC (866005)