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Aerosol Jet Printing as a Versatile Sample Preparation Method for Operando Electrochemical TEM Microdevices

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cam.issuedOnline2022-06-17
dc.contributor.authorMorzy, JK
dc.contributor.authorSartor, A
dc.contributor.authorDose, WM
dc.contributor.authorOu, C
dc.contributor.authorKar-Narayan, S
dc.contributor.authorDe Volder, MFL
dc.contributor.authorDucati, C
dc.contributor.orcidMorzy, JK [0000-0003-0770-461X]
dc.contributor.orcidDose, WM [0000-0003-3850-0505]
dc.contributor.orcidKar-Narayan, S [0000-0002-8151-1616]
dc.contributor.orcidDe Volder, MFL [0000-0003-1955-2270]
dc.contributor.orcidDucati, C [0000-0003-3366-6442]
dc.date.accessioned2022-06-18T08:00:20Z
dc.date.available2022-06-18T08:00:20Z
dc.date.issued2022
dc.date.submitted2022-03-09
dc.date.updated2022-06-18T08:00:20Z
dc.descriptionFunder: Royce Cluster Tool
dc.description.abstract<jats:title>Abstract</jats:title><jats:p><jats:italic>Operando</jats:italic> electrochemical transmission electron microscopy (ec‐TEM) is a promising tool for advanced characterization of energy systems close to their operating conditions. However, reliable sample preparation for the technique is particularly challenging due to spatial constraints. Here, a novel approach of manufacturing such samples is introduced and demonstrated for industrially relevant battery powders: NMC811 and LTO (LiNi<jats:sub>0.8</jats:sub>Mn<jats:sub>0.1</jats:sub>Co<jats:sub>0.1</jats:sub>O<jats:sub>2</jats:sub> and Li<jats:sub>4</jats:sub>Ti<jats:sub>5</jats:sub>O<jats:sub>12</jats:sub>). Aerosol‐jet printing is used to deposit microscale patterns of battery active material particles on the electrodes of commercial ec‐TEM chips. This method provides high spatial resolution (line width &lt; 30 µm) and accuracy, ease of ink preparation, flexibility of materials, and ability to manufacture complex structures (layered or mixed materials). Size selectivity of aerosol jet printing and its positive implications for ec‐TEM sample preparation are also discussed. This procedure is a promising solution to the difficult problem of micro‐battery fabrication for ec‐TEM and for other applications where high spatial resolution deposition from powders is required.</jats:p>
dc.identifier.doi10.17863/CAM.85634
dc.identifier.eissn2196-7350
dc.identifier.issn2196-7350
dc.identifier.otheradmi202200530
dc.identifier.urihttps://www.repository.cam.ac.uk/handle/1810/338222
dc.languageen
dc.language.isoeng
dc.publisherWiley
dc.publisher.urlhttp://dx.doi.org/10.1002/admi.202200530
dc.subjectaerosol jet printing
dc.subjectbatteries
dc.subjectelectrochemistry
dc.subjectmicrodevices
dc.subjectmicrodevice fabrication
dc.subjectoperando TEM
dc.titleAerosol Jet Printing as a Versatile Sample Preparation Method for Operando Electrochemical TEM Microdevices
dc.typeArticle
prism.publicationNameAdvanced Materials Interfaces
pubs.funder-project-idEngineering and Physical Sciences Research Council (EP/L015978/1)
pubs.funder-project-idEngineering and Physical Sciences Research Council (EP/P024947/1)
pubs.funder-project-idEuropean Commission Horizon 2020 (H2020) Research Infrastructures (RI) (823717)
pubs.funder-project-idEngineering and Physical Sciences Research Council (EP/S019367/1)
pubs.funder-project-idEngineering and Physical Sciences Research Council (EP/R00661X/1)
pubs.funder-project-idEPSRC (via University of Manchester) (EP/X527257/1)
rioxxterms.licenseref.urihttp://creativecommons.org/licenses/by/4.0/
rioxxterms.versionVoR
rioxxterms.versionofrecord10.1002/admi.202200530

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