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Excitonic Insulator to Superconductor Phase Transition in Ultra-Compressed Helium

Accepted version
Peer-reviewed

Type

Article

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Authors

Pickard, Christopher  ORCID logo  https://orcid.org/0000-0002-9684-5432
Conway, Lewis 
Monserrat Sanchez, Bartomeu 

Abstract

Helium, the second most abundant element in the universe, exhibits an extremely large electronic band gap of about 20 eV at ambient pressures. While the metallization pressure of helium has been accurately determined, thus far little attention has been paid to the specific mechanisms driving the band-gap closure and electronic properties of this quantum crystal in the terapascal regime (1 TPa = 10 Mbar). Here, we employ density functional theory and many-body perturbation calculations to fill up this knowledge gap. It is found that prior to reaching metallicity helium becomes an excitonic insulator (EI), an exotic state of matter in which electrostatically bound electron-hole pairs may form spontaneously. Furthermore, we predict metallic helium to be a superconductor with a critical temperature of ≈ 20 K just above its metallization pressure and of ≈ 70 K at 100 TPa. These unforeseen phenomena may be critical for improving our fundamental understanding and modelling of celestial bodies.

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Keywords

Journal Title

Nature Communications

Conference Name

Journal ISSN

2041-1723

Volume Title

Publisher

Nature Portfolio
Sponsorship
Engineering and Physical Sciences Research Council (EP/P022596/1)
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