Generalised boundary conditions for hydrogen transport at crack tips
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Authors
Díaz, Andres
Wright, Louise
Turnbull, Alan
Abstract
We present a generalised framework for resolving the electrochemistry-diffusion interface and modelling hydrogen transport near a crack tip. The adsorption and absorption kinetics are captured by means of Neumann-type generalised boundary conditions. The diffusion model includes the role of trapping, with a constant or evolving trap density, and the influence of the hydrostatic stress. Both conventional plasticity and strain gradient plasticity are used to model the mechanical behaviour of the solid. Notable differences are found in the estimated crack tip hydrogen concentrations when comparing with the common procedure of prescribing a constant hydrogen concentration at the crack surfaces.
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Keywords
cond-mat.mtrl-sci, cond-mat.mtrl-sci
Journal Title
Corrosion Science
Conference Name
Journal ISSN
0010-938X
1879-0496
1879-0496
Volume Title
173
Publisher
Elsevier
Publisher DOI
Sponsorship
EPSRC (via Imperial College London) (EP/R010161/1)