Route to High-Performance Micro-solid Oxide Fuel Cells on Metallic Substrates.


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Article
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Authors
Lovett, Adam J 
Chalklen, Thomas 
Abstract

Micro-solid oxide fuel cells based on thin films have strong potential for use in portable power devices. However, devices based on silicon substrates typically involve thin-film metallic electrodes which are unstable at high temperatures. Devices based on bulk metal substrates overcome these limitations, though performance is hindered by the challenge of growing state-of-the-art epitaxial materials on metals. Here, we demonstrate for the first time the growth of epitaxial cathode materials on metal substrates (stainless steel) commercially supplied with epitaxial electrolyte layers (1.5 μm (Y2O3)0.15(ZrO2)0.85 (YSZ) + 50 nm CeO2). We create epitaxial mesoporous cathodes of (La0.60Sr0.40)0.95Co0.20Fe0.80O3 (LSCF) on the substrate by growing LSCF/MgO vertically aligned nanocomposite films by pulsed laser deposition, followed by selectively etching out the MgO. To enable valid comparison with the literature, the cathodes are also grown on single-crystal substrates, confirming state-of-the-art performance with an area specific resistance of 100 Ω cm2 at 500 °C and activation energy down to 0.97 eV. The work marks an important step toward the commercialization of high-performance micro-solid oxide fuel cells for portable power applications.

Description
Keywords
commercially viable, epitaxial thin film, high-performance, metallic substrate, solid oxide fuel cell
Journal Title
ACS Appl Mater Interfaces
Conference Name
Journal ISSN
1944-8244
1944-8252
Volume Title
13
Publisher
American Chemical Society (ACS)
Rights
All rights reserved
Sponsorship
European Commission (280432)
Engineering and Physical Sciences Research Council (EP/P007767/1)
European Research Council (779444)
European Research Council (639526)
ESRC (ES/T008989/1)
Royal Academy of Engineering (RAEng) (CiET1819\24)
EPSRC (2108857)
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