Formation of a meltable purinate metal–organic framework and its glass analogue †
The chemistries that can be incorporated within melt-quenched zeolitic imidazolate framework (ZIF) glasses are currently limited. Here we describe the preparation of a previously unknown purine-containing ZIF which we name ZIF-UC-7. We find that it melts and forms a glass at one of the lowest temperatures reported for 3D hybrid frameworks.
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Royal Society (RGF\EA\180092, RGS\R2\212221, RSG\R1\180395, UF110655, UF150021, UF160394)
Leverhulme Trust (RPG-2020-005)
Cambridge Trust (304253100)
Corning Incorporated Foundation (Unassigned)
University of Glasgow (Unassigned)