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Catalytic Control of Plastic Flow in Siloxane-Based Liquid Crystalline Elastomer Networks.

Accepted version
Peer-reviewed

Type

Article

Change log

Authors

Saed, Mohand O 
Terentjev, Eugene M  ORCID logo  https://orcid.org/0000-0003-3517-6578

Abstract

Liquid crystalline elastomer networks cross-linked by dynamic covalent bonds (xLCE) have the ability to be (re)processed during the plastic flow. However, the current bond-exchange strategies that are used to induce plastic flow in xLCE lack the efficient method to control the elastic-plastic transition. Here we describe a straightforward method to manipulate the transition to plastic flow via the choice of catalyst in xLCE cross-linked by siloxane. The nature and the amount of catalyst have a profound effect on the elastic-plastic transition temperature, and the stress relaxation behavior of the network. The temperature of fast plastic flow and the associated bond-exchange activation energy varied from 120 °C and 83 kJ/mol in the "fastest" exchange promoted by triazobicyclodecene (TBD) to 240 °C and 164 kJ/mol in the "slowest" exchange with triphenylphosphine (PPH), with a range of catalysts in between. We have identified the optimum conditions for programming an aligned monodomain xLCE, high programming temperature (230 °C) and low nematic to isotropic transition (60 °C), to achieve thermally and mechanically stable actuators.

Description

Keywords

3403 Macromolecular and Materials Chemistry, 34 Chemical Sciences

Journal Title

ACS Macro Lett

Conference Name

Journal ISSN

2161-1653
2161-1653

Volume Title

9

Publisher

American Chemical Society (ACS)

Rights

All rights reserved
Sponsorship
European Research Council (786659)
European Research Council H2020