Rotational Dynamics of Desorption: Methane and Ethane at Stepped and Kinked Platinum Surfaces


Type
Article
Change log
Abstract

When the interactions between surfaces and adsorbates are studied, molecular rotations are often neglected. In this work, we carefully analyse the rotational dynamics of methane and ethane molecules desorbing from two different platinum surfaces by means of first-principles molecular dynamics simulations. With respect to its rotational symmetry, methane - a benchmark system for adsorption dynamics - constitutes a spherical top and ethane is a symmetric top. We focus upon the achiral Pt{110}-(1x2) surface, which exhibits both mirror symmetry and a stepped geometry, and upon the chiral Pt{531} surface, which exhibits kink sites and lacks reflection symmetry. For methane, neither a strong nor directed angular momentum is induced by either of the two surfaces, whereas for ethane we find an increased directionality for the molecular rotation upon desorption from Pt{531} compared to Pt{110}-(1x2). The principle of microscopic reversibility implies that such results (in time reversal) will also be relevant to the process of adsorption, which would therefore be sensitive to the initial rotational state of incoming molecules.

Description
Keywords
34 Chemical Sciences, 3406 Physical Chemistry
Journal Title
Journal of Physical Chemistry C
Conference Name
Journal ISSN
1932-7447
1932-7455
Volume Title
125
Publisher
American Chemical Society (ACS)
Sponsorship
EPSRC (2112388)