We introduce a geometric analysis of turbulent mixing in density-stratified flows based on the alignment of the density gradient in two orthogonal bases that are locally constructed from the velocity gradient tensor. The first basis connects diapycnal mixing to rotation and shearing motions, building on the recent 'rortex--shear decomposition' in stratified shear layers (Jiang et al. \textit{J. Fluid Mech.}, \textbf{947}, A30, 2022), while the second basis connects mixing to the principal axes of the viscous dissipation tensor. Applying this framework to datasets taken in the stratified inclined duct laboratory experiment reveals that density gradients in locations of high shear tend to align preferentially (i) along the direction of minimum dissipation and (ii) normal to the plane spanned by the rotex and shear vectors. The analysis of the local alignment across increasingly turbulent flows offers new insights into the intricate relationship between the density gradient and dissipation, and thus diapycnal mixing.