Endogenous Metal-Ion Dynamic Nuclear Polarization for NMR Signal Enhancement in Metal Organic Frameworks
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Peer-reviewed
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Rational design of metal-organic framework (MOF)-based materials for catalysis, gas capture and storage, requires deep understanding of the host-guest interactions between the MOF and the adsorbed molecules. Solid-State NMR spectroscopy...
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Acknowledgements: We thank Dr Alexander C. Forse for access to the CO2 adsorption measurements. I. B. M. is grateful to the Sustainability and Energy Research Initiative (SAERI) fellowship for financial support. This research was funded by the European Research Council (MIDNP, Grant 803024), the European Union's Horizon 2020 research and innovation program (Pan-European Solid-State NMR Infrastructure for Chemistry-Enabling Access, PANACEA, Grant Agreement 101008500) and the Clore Institute for High Field Magnetic Resonance Spectroscopy and Imaging. Dr Daniel Jardón-Álvarez is acknowledged for valuable discussions and the help with data processing. We also thank Dr Ayan Maity for acquiring the SEM images. The work was made possible in part by the historic generosity of the Harold Perlman family.
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2041-6539
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