Isomerisation, reactivity and coordination chemistry of a new hybrid, multi-functional phosphazane.
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Peer-reviewed
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Abstract
The unsymmetric PIII/PV cyclodiphosphazane framework [(S[double bond, length as m-dash])(H)P(μ-NtBu)2PNHtBu] (2) provides entry into the mixed chalgogenide dianion [(S)P(μ-NtBu)2P(Se)NtBu]2-, and unique insight into the mechanisms of cis/trans isomerism in phosph(iii)- and phosph(v)-azanes.
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Dalton Trans
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1477-9226
1477-9234
1477-9234
Volume Title
46
Publisher
Royal Society of Chemistry (RSC)
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Engineering and Physical Sciences Research Council (EP/K039520/1)