Repository logo
 

Preparation of a porphyrinic bis(pyridyl aldehyde) and its supramolecular complexes.


Change log

Authors

Greaves, Christopher R 
Alemán García, Miguel Á 
Bampos, Nick 

Abstract

Shape-specific molecular assemblies require the preparation of the constituent building blocks with the necessary properties to bias exclusive formation of the proposed structures. In this work, a novel linear porphyrin dialdehyde was synthesised and used to assemble a supramolecular grid via Cu(i) heteroleptic phenanthroline/pyridyl imine complexation, and a tetrahedral cage via Fe(ii) pyridyl imine coordination.

Description

Keywords

0303 Macromolecular and Materials Chemistry, 0305 Organic Chemistry, 0302 Inorganic Chemistry

Journal Title

Chem Commun (Camb)

Conference Name

Journal ISSN

1359-7345
1364-548X

Volume Title

51

Publisher

Royal Society of Chemistry (RSC)
Sponsorship
We gratefully acknowledge funding from the Consejo Nacional de Ciencia y Tecnologia (CONACYT) Mexico (MAAG) and the Cambridge NanoDTC (CRG).