Preparation of a porphyrinic bis(pyridyl aldehyde) and its supramolecular complexes.
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Authors
Greaves, Christopher R
Alemán García, Miguel Á
Bampos, Nick
Abstract
Shape-specific molecular assemblies require the preparation of the constituent building blocks with the necessary properties to bias exclusive formation of the proposed structures. In this work, a novel linear porphyrin dialdehyde was synthesised and used to assemble a supramolecular grid via Cu(i) heteroleptic phenanthroline/pyridyl imine complexation, and a tetrahedral cage via Fe(ii) pyridyl imine coordination.
Description
Keywords
0303 Macromolecular and Materials Chemistry, 0305 Organic Chemistry, 0302 Inorganic Chemistry
Journal Title
Chem Commun (Camb)
Conference Name
Journal ISSN
1359-7345
1364-548X
1364-548X
Volume Title
51
Publisher
Royal Society of Chemistry (RSC)
Publisher DOI
Sponsorship
We gratefully acknowledge funding from the Consejo Nacional de Ciencia y Tecnologia (CONACYT) Mexico (MAAG) and the Cambridge NanoDTC (CRG).