Adsorption and Reaction Microcalorimetry on Nickel and Platinum Single Crystal Surfaces
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Abstract
The unique Cambridge single crystal adsorption microcalorimeter has been applied to a range of systems of catalytic interest to extract fundamental thermodynamic data. Coverage-dependent adsorption heats and sticking probabilities have been obtained with CO, NO, oxygen and ethylene adsorbates and Pt{110}, Ni{100}, Ni{110} and K/Ni{110} substrates. The initial adsorption heats for CO, NO, and O2 on Pt{110} are 183, 160 and 335 kJ mol