Selective lithium halide ion-pair sensing by a dynamic metalloporphyrin [2]rotaxane

A dynamic zinc(II) metalloporphyrin axle-containing [2]rotaxane with a heteroditopic macrocycle component is shown to selectively recognise and optically sense lithium halide (LiX) ion-pair species. 1H NMR and UV-visible absorption experiments...

Description

Acknowledgements: J. T. W. thanks the EPSRC for funding (Centre for Doctoral Training in Inorganic Chemistry for Future Manufacturing (OxICFM, EP/S023828/1) and a Doctoral Prize Award (EP/W524311/1)). A. D. thanks the EPSRC for a studentship (EP/N509711/1). Andrew J. Taylor, University of Oxford, is thanked for useful discussions.

Keywords

3403 Macromolecular and Materials Chemistry, 3405 Organic Chemistry, 34 Chemical Sciences

Journal Title

Dalton Transactions

Journal ISSN

1477-9226
1477-9234

Publisher

Royal Society of Chemistry (RSC)

Publisher DOI

https://doi.org/10.1039/d4dt03026e

Rights and licensing

Except where otherwised noted, this item's license is described as https://creativecommons.org/licenses/by/3.0/

Sponsorship

Engineering and Physical Sciences Research Council (EP/S023828/1, EP/W524311/1, EP/N509711/1)

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