We construct perfect zero-knowledge probabilistically checkable proofs (PZK-PCPs) for every language in #P. This is the first construction of a PZK-PCP for any language outside BPP. Furthermore, unlike previous constructions of (statistical) zero-knowledge PCPs, our construction simultaneously achieves non-adaptivity and zero knowledge against arbitrary (adaptive) polynomial-time malicious verifiers. Our construction consists of a novel masked sumcheck PCP, which uses the combinatorial nullstellen- satz to obtain antisymmetric structure within the hypercube and randomness outside of it. To prove zero knowledge, we introduce the notion of locally simulatable encodings: randomised encodings in which every local view of the encoding can be efficiently sampled given a local view of the message. We show that the code arising from the sumcheck protocol (the Reed–Muller code augmented with subcube sums) admits a locally simulatable encoding. This reduces the algebraic problem of simulating our masked sumcheck to a combinatorial property of antisymmetric functions.