Bimetallic copper palladium nanorods: plasmonic properties and palladium content effects
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Abstract
Cu is an inexpensive alternative plasmonic metal with optical behaviour comparable to Au but with much poorer environmental stability. Alloying with a more stable metal can improve stability and add functionality, with potential effects on the plasmonic properties. Here we investigate the plasmonic behaviour of Cu nanorods and Cu-CuPd nanorods containing up 46 mass percent Pd. Monochromated scanning transmission electron microscopy electron energy-loss spectroscopy first reveals the strong length dependence of multiple plasmonic modes in Cu nanorods, where the plasmon peaks redshift and narrow with increasing length. Next, we observe an increased damping (and increased linewidth) with increasing Pd content, accompanied by minimal frequency shift. These results are corroborated by and expanded upon with numerical simulations using the electron-driven discrete dipole approximation. This study indicates that adding Pd to nanostructures of Cu is a promising method to expand the scope of their plasmonic applications.
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Acknowledgements: The authors wish to acknowledge Dr Jason Day for performing ICP-MS measurements. CAW is supported by a Royal Society Newton International Fellowship (NIF-R1-211474). ERH is thankful for funding from the Engineering and Physical Sciences Research Council (EPSRC) NanoDTC Cambridge (EP/L015978/1). ER acknowledges support from the EU Framework Programme for Research and Innovation Horizon 2020 (ERC Starting Grant SPECs 804523). XY, SJ, YW, and BZ acknowledge support from the U.S. National Science Foundation under grant number CHE-2239441. SJ thanks the Robert & Marjorie Mann Fellowship from Indiana University. SuperSTEM is the National Research Facility for Advanced Electron Microscopy, supported by the EPSRC through grants numbers EP/W021080/1 and EP/V036432/1.
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2516-0230
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Royal Society (NIF\R1\211474)
Engineering and Physical Sciences Research Council (EP/L015978/1)
European Research Council (804523)