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Impedance-based sensor for potassium ions.

Accepted version
Peer-reviewed

Type

Article

Change log

Authors

Day, C 
Søpstad, S 
Nathan, A 

Abstract

A conductometric sensor for potassium ions in solution is presented. Interdigitated, planar gold electrodes were coated with a potassium-selective polymer membrane composed of a poly(vinyl chloride) matrix with about 65 wt% of plasticiser and 2-5 wt% of a potassium-selective ionophore. The impedance of the membrane was measured, using the electrodes as a transducer, and related to the concentration of potassium in a sample solution in contact with the membrane. Sensitivity was optimised by varying the sensor components, and selectivity for potassium over sodium was also shown. The resulting devices are compact, miniature, robust sensors which, by means of impedance measurements, eliminate the need for a reference electrode. The sensor was tested for potassium concentration changes of 2 mM across the clinically relevant range of 2.7-18.7 mM.

Description

Keywords

Blood analysis, Conductometric sensor, Impedance spectroscopy, Ion-selective membrane, Portable sensor, Potassium, Electric Impedance, Electrochemical Techniques, Ions, Potassium

Journal Title

Anal Chim Acta

Conference Name

Journal ISSN

0003-2670
1873-4324

Volume Title

1034

Publisher

Elsevier BV
Sponsorship
Kidney Research UK (RP_053_20160307)
Henslow Fellowship, Darwin College, Cambridge L'Oreal -UNESCO UK & Ireland Fellowship For Women In Science