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Liquid phase blending of metal-organic frameworks.

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cam.issuedOnline2018-06-15
dc.contributor.authorLongley, Louis
dc.contributor.authorCollins, Sean M
dc.contributor.authorZhou, Chao
dc.contributor.authorSmales, Glen J
dc.contributor.authorNorman, Sarah E
dc.contributor.authorBrownbill, Nick J
dc.contributor.authorAshling, Christopher W
dc.contributor.authorChater, Philip A
dc.contributor.authorTovey, Robert
dc.contributor.authorSchönlieb, Carola-Bibiane
dc.contributor.authorHeaden, Thomas F
dc.contributor.authorTerrill, Nicholas J
dc.contributor.authorYue, Yuanzheng
dc.contributor.authorSmith, Andrew J
dc.contributor.authorBlanc, Frédéric
dc.contributor.authorKeen, David A
dc.contributor.authorMidgley, Paul A
dc.contributor.authorBennett, Thomas D
dc.contributor.orcidCollins, Sean M [0000-0002-5151-6360]
dc.contributor.orcidZhou, Chao [0000-0003-0218-3114]
dc.contributor.orcidChater, Philip A [0000-0002-5513-9400]
dc.contributor.orcidTovey, Robert [0000-0001-5411-2268]
dc.contributor.orcidTerrill, Nicholas J [0000-0002-8783-1282]
dc.contributor.orcidSmith, Andrew J [0000-0003-3745-7082]
dc.contributor.orcidBlanc, Frédéric [0000-0001-9171-1454]
dc.contributor.orcidKeen, David A [0000-0003-0376-2767]
dc.contributor.orcidBennett, Thomas D [0000-0003-3717-3119]
dc.date.accessioned2018-09-10T22:17:27Z
dc.date.available2018-09-10T22:17:27Z
dc.date.issued2018-06-15
dc.description.abstractThe liquid and glass states of metal-organic frameworks (MOFs) have recently become of interest due to the potential for liquid-phase separations and ion transport, alongside the fundamental nature of the latter as a new, fourth category of melt-quenched glass. Here we show that the MOF liquid state can be blended with another MOF component, resulting in a domain structured MOF glass with a single, tailorable glass transition. Intra-domain connectivity and short range order is confirmed by nuclear magnetic resonance spectroscopy and pair distribution function measurements. The interfacial binding between MOF domains in the glass state is evidenced by electron tomography, and the relationship between domain size and Tg investigated. Nanoindentation experiments are also performed to place this new class of MOF materials into context with organic blends and inorganic alloys.
dc.format.mediumElectronic
dc.identifier.doi10.17863/CAM.27441
dc.identifier.eissn2041-1723
dc.identifier.issn2041-1723
dc.identifier.urihttps://www.repository.cam.ac.uk/handle/1810/280077
dc.languageeng
dc.language.isoeng
dc.publisherSpringer Science and Business Media LLC
dc.publisher.urlhttp://dx.doi.org/10.1038/s41467-018-04553-6
dc.rightsAttribution 4.0 International (CC BY 4.0)
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/
dc.subject0306 Physical Chemistry (incl. Structural)
dc.subject0299 Other Physical Sciences
dc.titleLiquid phase blending of metal-organic frameworks.
dc.typeArticle
dcterms.dateAccepted2018-05-10
prism.issueIdentifier1
prism.publicationDate2018
prism.publicationNameNat Commun
prism.startingPage2135
prism.volume9
pubs.funder-project-idRoyal Society (UF150021)
pubs.funder-project-idRoyal Society (RG160498)
pubs.funder-project-idCommonwealth Scientific and Industrial Research Organisation (CSIRO) (C2017/3108)
pubs.funder-project-idEngineering and Physical Sciences Research Council (EP/J009539/1)
pubs.funder-project-idEngineering and Physical Sciences Research Council (EP/N014588/1)
pubs.funder-project-idEngineering and Physical Sciences Research Council (EP/M00483X/1)
pubs.funder-project-idEuropean Research Council (291522)
pubs.funder-project-idEngineering and Physical Sciences Research Council (EP/L016516/1)
pubs.funder-project-idEPSRC (1937211)
rioxxterms.licenseref.startdate2018-06-15
rioxxterms.licenseref.urihttp://www.rioxx.net/licenses/all-rights-reserved
rioxxterms.typeJournal Article/Review
rioxxterms.versionVoR
rioxxterms.versionofrecord10.1038/s41467-018-04553-6

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