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Carbon dots as photosensitisers for solar-driven catalysis

Accepted version
Peer-reviewed

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Type

Article

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Authors

Hutton, G 
Martindale, B 

Abstract

Artificial photosynthesis is the mimicry of the natural process of solar energy conversion into chemical energy carriers. Photocatalytic systems that combine light-harvesting materials and catalysts in solution or suspension provide a promising route towards this goal. A key requirement for a sustainable solar fuel production system is a low-cost, stable and non-toxic light harvester. Photoluminescent carbon nanoparticles, carbon dots (CDs), are promising emerging light-harvesters for photocatalytic fuel production systems. CDs possess many desirable properties for this purpose, such as inexpensive, scalable synthetic routes, low-toxicity and tuneable surface chemistry. In this tutorial review, the integration of CDs in photocatalytic fuel generation systems with metallic, molecular and enzymatic catalysts is discussed. An overview of CD types, synthesis and properties is given along with a discussion of tuneable CD properties that can be optimised for applications in photocatalysis. Current understanding of the photophysical electron transfer processes present in CD photocatalytic systems is outlined and various avenues for their further development are highlighted.

Description

Keywords

0306 Physical Chemistry (incl. Structural), 0912 Materials Engineering, 0303 Macromolecular and Materials Chemistry, 0302 Inorganic Chemistry, 0305 Organic Chemistry

Journal Title

Chemical Society Reviews

Conference Name

Journal ISSN

0306-0012
1460-4744

Volume Title

46

Publisher

RSC
Sponsorship
Christian Doppler Forschungsgesellschaft (unknown)
Christian Doppler Research Association, OMV Group, Poynton PhD scholarship, Oppenheimer PhD scholarship