Corrosion and inhibition of copper in hydrocarbon solution on a molecular level investigated using neutron reflectometry and XPS
Published version
Peer-reviewed
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Authors
Welbourn, RJL
Truscott, CL
Skoda, MWA
Zarbakhsh, A
Clarke, SM
Abstract
© 2016 The Authors The behaviour and molecular structure of three organic additives adsorbed from oil onto a copper surface rich in copper (II) oxide is presented. The variation in the ability of these three agents to prevent corrosion of the copper oxide surface by exposure to sulphur is also included. A combination of visible observations, X-ray photoelectron spectroscopy (XPS) and neutron reflection (NR) are used to characterise both the adsorbed layer and underlying copper oxide. The model additives are chosen to represent ‘effective’, ‘intermediate’ and ‘ineffective’ inhibitors for copper.
Description
Keywords
A. Copper, A. Organic coatings, B. XPS, C. Oxidation, C. Oxide coatings
Journal Title
Corrosion Science
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Journal ISSN
0010-938X
1879-0496
1879-0496
Volume Title
115
Publisher
Elsevier
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This work was supported by the Engineering and Physical Sciences Research Council, UK (EPSRC) and BP plc [grant number EP/J501876/1].