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Strain gradient plasticity modeling of hydrogen diffusion to the crack tip

Accepted version
Peer-reviewed

Type

Article

Change log

Authors

Martínez-Pañeda, Emilio  ORCID logo  https://orcid.org/0000-0002-1562-097X
del Busto, S 
Niordson, C 
Betegon, C 

Abstract

© 2016 Hydrogen Energy Publications LLC. In this work hydrogen diffusion towards the fracture process zone is examined accounting for local hardening due to geometrically necessary dislocations (GNDs) by means of strain gradient plasticity (SGP). Finite element computations are performed within the finite deformation theory to characterize the gradient-enhanced stress elevation and subsequent diffusion of hydrogen towards the crack tip. Results reveal that GNDs, absent in conventional plasticity predictions, play a fundamental role on hydrogen transport ahead of a crack. SGP estimations provide a good agreement with experimental measurements of crack tip deformation and high levels of lattice hydrogen concentration are predicted within microns to the crack tip. The important implications of the results in the understanding of hydrogen embrittlement mechanisms are thoroughly discussed.

Description

Keywords

Strain gradient plasticity, Hydrogen embrittlement, Fracture mechanics, Hydrogen diffusion, Finite element analysis

Journal Title

International Journal of Hydrogen Energy

Conference Name

Journal ISSN

0360-3199
1879-3487

Volume Title

41

Publisher

Elsevier BV