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dc.contributor.authorSlavchov, RI
dc.contributor.authorNovev, JK
dc.contributor.authorMosbach, S
dc.contributor.authorKraft, M
dc.date.accessioned2018-10-10T05:20:09Z
dc.date.available2018-10-10T05:20:09Z
dc.date.issued2018
dc.identifier.issn0888-5885
dc.identifier.urihttps://www.repository.cam.ac.uk/handle/1810/283474
dc.description.abstract© 2018 American Chemical Society. A model of the temperature dependence of the vapor pressure and the heat of vaporization of liquids whose vapors contain associates is presented for two cases: dimers and linear associates in the gas phase. The results are analytic generalizations of the Clausius-Clapeyron equation, valid with accuracy of 0.1%-1%, as demonstrated with 11 liquids: formic and acetic acids, methanol, ethanol, n-propanol, n-butanol, water, benzene, toluene, heptane, and isooctane. The model involves only readily available handbook parameters: the room-temperature heat of vaporization, vapor pressure, heat capacities, second virial coefficient, and heat of dissociation of the dimers in the gas phase.
dc.description.sponsorshipThe authors acknowledge the funding and technical support from BP through the BP International Centre for Advanced Materials (BP-ICAM), which made this research possible. This research is partially funded by the National Research Foundation (NRF), Prime Minister’s Office, Singapore under its Campus for Research Excellence and Technological Enterprise (CREATE) programme. J.K.N. thanks Trinity College and the Clarendon Fund of the University of Oxford for a Clarendon–Titley Scholarship.
dc.publisherAmerican Chemical Society (ACS)
dc.titleVapor Pressure and Heat of Vaporization of Molecules That Associate in the Gas Phase
dc.typeArticle
prism.endingPage5731
prism.issueIdentifier16
prism.publicationDate2018
prism.publicationNameIndustrial and Engineering Chemistry Research
prism.startingPage5722
prism.volume57
dc.identifier.doi10.17863/CAM.30840
dcterms.dateAccepted2018-03-27
rioxxterms.versionofrecord10.1021/acs.iecr.7b04241
rioxxterms.licenseref.urihttp://www.rioxx.net/licenses/all-rights-reserved
rioxxterms.licenseref.startdate2018-04-25
dc.contributor.orcidSlavchov, RI [0000-0002-4639-1225]
dc.contributor.orcidKraft, M [0000-0002-4293-8924]
dc.identifier.eissn1520-5045
rioxxterms.typeJournal Article/Review
cam.issuedOnline2018-03-27
rioxxterms.freetoread.startdate2019-04-25


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