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dc.contributor.authorY Yuen, Alexander
dc.contributor.authorPorcarelli, Luca
dc.contributor.authorH Aguirresarobe, Robert
dc.contributor.authorSanchez-Sanchez, Ana
dc.contributor.authorDel Agua, Isabel
dc.contributor.authorIsmailov, Usein
dc.contributor.authorG Malliaras, George
dc.contributor.authorMecerreyes, David
dc.contributor.authorIsmailova, Esma
dc.contributor.authorSardon, Haritz
dc.date.accessioned2018-11-16T00:30:19Z
dc.date.available2018-11-16T00:30:19Z
dc.date.issued2018-09-05
dc.identifier.issn2073-4360
dc.identifier.urihttps://www.repository.cam.ac.uk/handle/1810/285115
dc.description.abstractIn recent years, gels based on ionic liquids incorporated into polymer matrices, namely iongels, have emerged as long-term contact media for cutaneous electrophysiology. Iongels possess high ionic conductivity and negligible vapor pressure and can be designed on demand. In spite of the extensive efforts devoted to the preparation of biodegradable ionic liquids, the investigations related to the preparation of iongels based on biodegradable polymers remain scarce. In this work, biodegradable polycarbonate-based iongels are prepared by ring-opening polymerization of N-substituted eight ring membered cyclic carbonate monomers in the presence of imidazolium lactate ionic liquid. Our iongels are able to take up 10⁻30 wt % of ionic liquid and become softer materials by increasing the amount of free ionic liquid. Rheological measurements showed that the cross-over point between the storage modulus G' and loss modulus G″ occurs at lower angular frequencies when the loading of free ionic liquid increases. These gels are able to take up to 30 wt % of the ionic liquid and the ionic conductivity of these gels increased up to 5 × 10-4 S·cm-1 at 25 °C as the amount of free ionic liquid increased. Additionally, we assess the biodegradation studies of the iongels by immersing them in water. The iongels decrease the impedance with the human skin to levels that are similar to commercial Ag/AgCl electrodes, allowing an accurate physiologic signals recording. The low toxicity and biodegradability of polycarbonate-based iongels make these materials highly attractive for cutaneous electrophysiology applications.
dc.format.mediumElectronic
dc.languageeng
dc.publisherMDPI AG
dc.rightsAttribution 4.0 International
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/
dc.titleBiodegradable Polycarbonate Iongels for Electrophysiology Measurements.
dc.typeArticle
prism.issueIdentifier9
prism.publicationDate2018
prism.publicationNamePolymers (Basel)
prism.volume10
dc.identifier.doi10.17863/CAM.32486
dcterms.dateAccepted2018-08-30
rioxxterms.versionofrecord10.3390/polym10090989
rioxxterms.licenseref.urihttp://www.rioxx.net/licenses/all-rights-reserved
rioxxterms.licenseref.startdate2018-09-05
dc.contributor.orcidPorcarelli, Luca [0000-0002-1624-382X]
dc.contributor.orcidSanchez-Sanchez, Ana [0000-0001-6871-5860]
dc.contributor.orcidMecerreyes, David [0000-0002-0788-7156]
dc.contributor.orcidIsmailova, Esma [0000-0001-6722-6782]
dc.identifier.eissn2073-4360
rioxxterms.typeJournal Article/Review
pubs.funder-project-idEuropean Commission Horizon 2020 (H2020) Marie Sk?odowska-Curie actions (742865)
cam.issuedOnline2018-09-05


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Attribution 4.0 International
Except where otherwise noted, this item's licence is described as Attribution 4.0 International