We will be undertaking essential maintenance work on Apollo's infrastructure on Thursday 14 August and Friday 15 August, therefore expect intermittent access to Apollo's content and search interface during that time. Please also note that Apollo's "Request a copy" service will be temporarily disabled while we undertake this work.
Repository logo
 

Research data supporting "Near-infrared luminescent open-shell π-conjugated systems with a lowest-energy zwitterionic singlet excited state"

Repository URI

https://www.repository.cam.ac.uk/handle/1810/367510

Repository DOI

https://doi.org/10.17863/CAM.108078
Thumbnail Image

Files

MainText-RawData.zip (54.49 MB)

Type

Dataset

Change log

Authors

Yu, Craig  ORCID logo  https://orcid.org/0000-0002-1423-5244

Description

The compressed (.zip) folder contains solution-state absorption and emission spectra of (M2TTM)2–CDT and p(M1TTM–CDT), and their time-dependent UV-vis absorption spectra in toluene with a concentration of 5.0 × 10-5 M. solution-state UV-vis absorption spectrum of M2TTM–CDT–Ph in toluene and its DFT calculation files. Solution-state temperature-variant EPR in toluene with a concentration of 50 um, and solid-state SQUID data with their fitting parameters. Cyclic voltammograms in both solution and film states as well as electrochromic switching data.

Version

Software / Usage instructions

Microsoft Excel, Microsoft Word, GaussView

Keywords

Correlated unpaired electrons, Electrochromic switching, Lowest-energy zwitterionic singlet excited state, Near-infrared absorption and emission, Open-shell π-conjugated systems

Publisher

Rights and licensing

Attribution 4.0 International (CC BY 4.0)
Except where otherwised noted, this item's license is described as Attribution 4.0 International (CC BY 4.0)

Relationships

Supplements:
https://www.repository.cam.ac.uk/handle/1810/369504

Collections

Research Data - Chemistry