Research data supporting [Unveiling the role of boroxines in metal-free carbon-carbon homologations using diazo compounds and boronic acid]
By means of computational and experimental mechanistic studies the fundamental role of boroxines in the reaction between diazo compounds and boronic acids was elucidated. Consequently, a selective metalfree carbon–carbon homologation of aryl and vinyl boroxines using TMSCHN2, giving access to TMSpinacol boronic ester products, was developed.
Software / Usage instructions
Engineering and Physical Sciences Research Council (EP/M004120/1)