Scholarly Works - Chemistry
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Sequence-Selective Formation of Synthetic H-Bonded Duplexes
(American Chemical Society, 2017-09-13)Oligomers equipped with a sequence of phenol and pyridine N-oxide groups form duplexes via H-bonding interactions between these recognition units. Reductive amination chemistry was used to synthesize all possible 3-mer ... -
Effect of DMSO on Protein Structure and Interactions Assessed by Collision-Induced Dissociation and Unfolding
Given the frequent use of DMSO in biochemical and biophysical assays, it is desirable to understand the influence of DMSO concentration on the dissociation or unfolding behavior of proteins. In this study, the effects of ... -
Environment-Dependent Radiation Damage in Atmospheric Pressure X-ray Spectroscopy
Atmospheric pressure x-ray spectroscopy techniques based on soft x-ray excitation can provide interface-sensitive chemical information about a solid surface immersed in a gas or liquid environment. However, x-ray illumination ... -
Transfer Hydrogenation of ortho-Hydroxybenzophenone Ketimines Catalysed by BINOL-derived Phosphoric Acid Occurs by a 14-Membered Bifunctional Transition Structure
(Royal Society of Chemistry, 2017-07-28)Chiral BINOL-derived phosphoric acids catalyse the transfer hydrogenation of ketimines using Hantszch esters. In many cases the nitrogen on the imine binds to the catalyst through the catalyst hydroxyl group and the ...
