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Young's modulus, Poisson's ratio, and residual stress and strain in (111)-oriented scandium nitride thin films on silicon


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Type

Article

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Authors

Moram, MA 
Barber, ZH 
Humphreys, CJ 
Joyce, TB 
Chalker, PR 

Abstract

Epitaxial scandium nitride films (225 nm thick) were grown on silicon by molecular beam epitaxy, using ammonia as a reactive nitrogen source. The main crystallographic orientation of ScN with respect to Si is (111)(ScN)parallel to(111)(Si) and 1-10parallel to0-11; however, some twinning is also present in the films. The films displayed a columnar morphology with rough surfaces, due to low adatom mobility during growth. The strain-free lattice parameter of ScN films grown under optimized conditions was found to be 4.5047 +/- 0.0005 A, as determined using high-resolution x-ray diffraction (HRXRD). In-plane and out-of-plane strains were subsequently evaluated using HRXRD and were used to determine the Poisson ratio of ScN along the < 111 > direction, which is found to be 0.188 +/- 0.005. Wafer curvature measurements were made and combined with the strain information to determine the average Young's modulus of the films, which is found to be 270 +/- 25 GPa. Residual film stresses ranged from -1 to 1 GPa (depending on film growth temperature and film thickness) due to competition between the tensile stress (induced by the differential thermal contraction between the ScN film and the Si substrate) and intrinsic compressive stresses generated during growth.

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Keywords

growth, evolution, microstructure, magnetron sputter-deposition, thermal-expansion, gallium nitride, hardness, electronic-properties, scn, scn(001)

Journal Title

Journal of Applied Physics

Conference Name

Journal ISSN

0021-8979
1089-7550

Volume Title

100

Publisher

AIP Publishing