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dc.contributor.authorTan, Nicholas Yen
dc.contributor.authorLi, Ruoyuen
dc.contributor.authorBräuer, Pierreen
dc.contributor.authorD’Agostino, Carmineen
dc.contributor.authorGladden, Lynnen
dc.contributor.authorZeitler, Axelen
dc.date.accessioned2015-04-21T10:30:45Z
dc.date.available2015-04-21T10:30:45Z
dc.date.issued2015-01-26en
dc.identifier.citationPhysical Chemistry Chemical Physics 2015,17, 5999-6008 DOI: 10.1039/C4CP04477Ken
dc.identifier.issn1463-9076
dc.identifier.urihttps://www.repository.cam.ac.uk/handle/1810/247401
dc.description.abstractTerahertz time-domain spectroscopy is used to explore hydrogen bonding structure and dynamics in binary liquid mixtures, spanning a range of protic–protic, protic–aprotic and aprotic–aprotic systems. A direct absorption coefficient analysis is compared against more complex Debye analysis and we observed good agreement of the two methods in determining the hydrogen bonding properties when at least one of the mixture components is protic. When both components are aprotic, we show that the trend in absorption coefficients match well with the theoretical trend in strength of hydrogen bond interactions predicted based on steric and electronic properties of the components.
dc.description.sponsorshipThe authors would like to acknowledge funding provided by EPSRC Grant EP/G011397/1.
dc.languageEnglishen
dc.language.isoenen
dc.publisherRoyal Society of Chemistry
dc.rightsAttribution 2.0 UK: England & Wales*
dc.rights.urihttp://creativecommons.org/licenses/by/2.0/uk/*
dc.titleProbing hydrogen-bonding in binary liquid mixtures with terahertz time-domain spectroscopy: a comparison of Debye and absorption analysisen
dc.typeArticle
dc.description.versionThis is the final published version. It first appeared at http://pubs.rsc.org/en/Content/ArticleLanding/2015/CP/c4cp04477k#!divAbstract.en
prism.endingPage6008
prism.publicationDate2015en
prism.publicationNamePhysical Chemistry Chemical Physicsen
prism.startingPage5999
prism.volume17en
dc.rioxxterms.funderEPSRC
dc.rioxxterms.projectidEP/G011397/1
rioxxterms.versionofrecord10.1039/C4CP04477Ken
rioxxterms.licenseref.urihttp://www.rioxx.net/licenses/all-rights-reserveden
rioxxterms.licenseref.startdate2015-01-26en
dc.contributor.orcidGladden, Lynn [0000-0001-9519-0406]
dc.contributor.orcidZeitler, Axel [0000-0002-4958-0582]
dc.identifier.eissn1463-9084
rioxxterms.typeJournal Article/Reviewen
pubs.funder-project-idEPSRC (EP/G011397/1)


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Attribution 2.0 UK: England & Wales
Except where otherwise noted, this item's licence is described as Attribution 2.0 UK: England & Wales