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dc.contributor.authorBrowne, Colmen
dc.contributor.authorRonson, Tanyaen
dc.contributor.authorNitschke, Jonathanen
dc.date.accessioned2015-12-10T17:50:49Z
dc.date.available2015-12-10T17:50:49Z
dc.date.issued2014-08-19en
dc.identifier.citationBrowne et al. Angewandte Chemie International Edition (2014) Vol. 53, pp. 10701-10705. doi:10.1002/anie.201406164en
dc.identifier.issn1433-7851
dc.identifier.urihttps://www.repository.cam.ac.uk/handle/1810/252956
dc.description.abstractThe reaction of 2,6-diformylpyridine with diverse amines and PdII ions gave rise to a variety of metallosupramolecular species, in which the PdII ion is observed to template a tridentate bis(imino)pyridine ligand. These species included a mononuclear complex as well as [2+2] and [3+3] macrocycles. The addition of pyridine-containing macrocyclic capping ligands allows for topological complexity to arise, thereby enabling the straightforward preparation of structures that include a [2]catenane, a [2]rotaxane, and a doubly threaded [3]rotaxane.
dc.description.sponsorshipThis work was underwritten by the Marie Curie Academic-Industrial Initial Training Network on Dynamic Molecular Nanostructures (DYNAMOL) of the European Union’s Seventh Framework Programme (FP7) and the UK Engineering and Physical Sciences Research Council (EPSRC). We thank the Cambridge Chemistry NMR service for experimental assistance, Diamond Light Source (UK) for synchrotron beamtime on I19 (MT7984), and the EPSRC National Crystallography Service for X-ray data collection.
dc.languageEnglishen
dc.language.isoenen
dc.publisherWiley
dc.subjectcatenanesen
dc.subjecthost–guest systemsen
dc.subjectrotaxanesen
dc.subjectself-assemblyen
dc.subjecttemplate synthesisen
dc.titlePalladium-Templated Subcomponent Self-Assembly of Macrocycles, Catenanes, and Rotaxanesen
dc.typeArticle
dc.description.versionThis is the final version of the article. It first appeared from Wiley via http://dx.doi.org/10.1002/anie.201406164en
prism.endingPage10705
prism.publicationDate2014en
prism.publicationNameAngewandte Chemie International Editionen
prism.startingPage10701
prism.volume53en
dc.rioxxterms.funderEPSRC
rioxxterms.versionofrecord10.1002/anie.201406164en
rioxxterms.licenseref.urihttp://www.rioxx.net/licenses/all-rights-reserveden
rioxxterms.licenseref.startdate2014-08-19en
dc.contributor.orcidRonson, Tanya [0000-0002-6917-3685]
dc.contributor.orcidNitschke, Jonathan [0000-0002-4060-5122]
dc.identifier.eissn1521-3773
rioxxterms.typeJournal Article/Reviewen
pubs.funder-project-idEPSRC (EP/K039520/1)
pubs.funder-project-idEPSRC (EP/J001163/1)


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