Research data supporting [Unveiling the role of boroxines in metal-free carbon-carbon homologations using diazo compounds and boronic acid]
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By means of computational and experimental mechanistic studies the fundamental role of boroxines in the reaction between diazo compounds and boronic acids was elucidated. Consequently, a selective metalfree carbon–carbon homologation of aryl and vinyl boroxines using TMSCHN2, giving access to TMSpinacol boronic ester products, was developed.
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Diazo, Boroxine, DFT, Homologation
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Engineering and Physical Sciences Research Council (EP/K009494/1)
Engineering and Physical Sciences Research Council (EP/M004120/1)
Engineering and Physical Sciences Research Council (EP/M004120/1)