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dc.contributor.authorGarden, JA
dc.contributor.authorPike, SD
dc.date.accessioned2018-05-10T15:28:38Z
dc.date.available2018-05-10T15:28:38Z
dc.date.issued2018-03-12
dc.identifier.issn1477-9226
dc.identifier.urihttps://www.repository.cam.ac.uk/handle/1810/275702
dc.description.abstractThe hydrolysis reaction between Brønsted basic organometallic or metal-amide reagents with Brønsted acidic OH groups from water or metal-hydroxides may act as a controlled stoichiometric strategy for the formation of M-O-M bonds, if careful consideration of reaction conditions is employed. This article explores the utilisation of highly reactive organometallic and metal-amide complexes from across the periodic table as reagents for the synthesis of metal-oxo clusters, oxo-bridged heterobimetallics and metal oxide nanoparticles. Such reactivity typically occurs at low temperatures with the release of hydrocarbon or amine by-products. The impact of ligand coordination, M-C bond strength, M-OH acidity and reaction temperature are discussed.
dc.format.mediumPrint
dc.languageeng
dc.publisherRoyal Society of Chemistry (RSC)
dc.titleHydrolysis of organometallic and metal-amide precursors: synthesis routes to oxo-bridged heterometallic complexes, metal-oxo clusters and metal oxide nanoparticles.
dc.typeArticle
prism.endingPage3662
prism.issueIdentifier11
prism.publicationDate2018
prism.publicationNameDalton Trans
prism.startingPage3638
prism.volume47
dc.identifier.doi10.17863/CAM.22967
dcterms.dateAccepted2018-02-24
rioxxterms.versionofrecord10.1039/c8dt00017d
rioxxterms.versionAM
rioxxterms.licenseref.urihttp://www.rioxx.net/licenses/all-rights-reserved
rioxxterms.licenseref.startdate2018-03
dc.contributor.orcidPike, Sebastian [0000-0002-9791-5244]
dc.identifier.eissn1477-9234
rioxxterms.typeJournal Article/Review
cam.issuedOnline2018
rioxxterms.freetoread.startdate2019-02-26


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