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Eliminating irreproducibility in SERS substrates

Accepted version
Peer-reviewed

Type

Article

Change log

Abstract

jats:titleAbstract</jats:title>jats:pIrreproducibility in surface‐enhanced Raman spectroscopy (SERS) due to variability among substrates is a source of recurrent debate within the field. It is regarded as a major hurdle towards the widespread adoption of SERS as a sensing platform. Most of the literature focused on developing substrates for various applications considers reproducibility of lower importance. Here, we address and analyse the sources of this irreproducibility in order to show how these can be minimised. We apply our findings to a simple substrate demonstrating reproducible SERS measurements with relative standard deviations well below 1% between different batches and days. Identifying the sources of irreproducibility and understanding how to reduce these can aid in the transition of SERS from the lab to real‐world applications.</jats:p>

Description

Keywords

cucurbituril, repeatability, reproducibility, self&#8208, assembly, SERS | plasmonics

Journal Title

Journal of Raman Spectroscopy

Conference Name

Journal ISSN

0377-0486
1097-4555

Volume Title

52

Publisher

Wiley

Rights

All rights reserved
Sponsorship
Engineering and Physical Sciences Research Council (EP/L027151/1)
Engineering and Physical Sciences Research Council (EP/P029426/1)
Engineering and Physical Sciences Research Council (EP/R020965/1)
Isaac Newton Trust (18.08(K))
Leverhulme Trust (ECF-2018-021)
Engineering and Physical Sciences Research Council (EP/L015889/1)
Engineering and Physical Sciences Research Council (EP/G060649/1)
Isaac Newton Trust Leverhulme Trust Winton Programme for the Physics of Sustainability Trinity College, University of Cambridge
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