The folder “Figure 2” contains the POM as a function of concentration at room temperature for C4C4E4, C4C4E6 and C8C4E4 and OriginPro.opj files containing the raw SAXS data (Intensity vs q).

The folder “Figure 4” gives the POM images for C4C4E6 as a function of increasing temperature.

The folder “Figure 6” gives the POM images for C2C4E4 and C8C8E4 as a function of irradiation (blue or UV).

The folder “Figure S1” gives the POM images and raw SAXS data for C2C4E4 as a function of concentration at room temperature.

The folder “Figure S2” gives the POM images and raw SAXS data for C6C4E4 as a function of concentration at room temperature.

The folder “Figure S4” gives the POM images for C8C8E4 as a function of concentration at room temperature.

The folder “Figure S5” provides the UV-Vis absorption spectra for C4C4E2 and C4C4E4. Additional UV-Vis data for the other AzoPS are available in the folder “UV-Vis”.

The folder “CMC” provides the raw dynamic light scattering (counts at a fixed measuring distance as a function of concentration) and surface tensiometry data, used to determine the critical micelle concentrations.

The folder “NMR” provides the proton and carbon NMR data used to characterise the AzoPS.

The folder “FTIR” provides the raw FTIR data used to characterise the AzoPS.

The folder “Mass Spec” provides the mass spectrometry data used to characterise the AzoPS.