Research data supporting "Insights into the electric double-layer capacitance of two-dimensional electrically conductive metal-organic frameworks"
Balhatchet, Chloe J
Golomb, Matthias J
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Gittins, J., Balhatchet, C. J., Chen, Y., Liu, C., Madden, D., Britto, S., Golomb, M. J., et al. (2021). Research data supporting "Insights into the electric double-layer capacitance of two-dimensional electrically conductive metal-organic frameworks" [Dataset]. https://doi.org/10.17863/CAM.71950
This data is primarily related to the synthesis and characterisation of Cu₃(HHTP)₂, and its electrochemical characterisation in symmetric electric double-layer capacitors with 1 M NEt₄BF₄ in acetonitrile electrolyte. The data provided here consists of: - CIF Files (contains information of the CIF files used during modelling and simulations. These can also be found at: https://doi.org/10.5281/zenodo.4694845). - Conductivity Measurement Data (contains results from the measurements used to calculate conductivity values). - Electrochemistry Data (contains CV data from 3-electrode cells; CV, GCD, EIS, and long-term cycling stability data from composite Cu₃(HHTP)₂ EDLCs with 1 M NEt₄BF₄ in acetonitrile electrolyte; CV, GCD, and EIS data from a Cu₃(HHTP)₂ EDLCs with 1 M NEt₄BF₄ in acetonitrile electrolyte; characterisation data for a YP50F EDLC with 1 M NEt₄BF₄ in acetonitrile; and characterisation data for an acetylene black EDLC with 1 M NEt₄BF₄ in acetonitrile). - Elemental Analysis Data (contains elemental analysis data). - Gas Sorption Data (.xlsx, .txt - contains results from gas sorption measurements). - XANES Data (contains XANES data from powder samples of Cu₃(HHTP)₂, pristine Cu₃(HHTP)₂ electrodes, cycled Cu₃(HHTP)₂ electrodes from EDLCs, and standard samples). - XRD Data (contains PXRD data).
- CIF files used for simulations - can be opened with a text file editor. - Conductivity measurement data - can be opened with a text file editor or Microsoft Excel. - Electrochemistry measurement data - can be opened with a text file editor or with EC-Lab. EC-Lab (Biologic) is not freely available. - Elemental analysis data - can be opened with a pdf reader, and a text file editor or Microsoft Excel. - Gas sorption isotherms - can be opened with a text file editor or Microsoft Excel. - XANES data - can be opened using the Athena program of the Demeter software package. This is free to download from https://bruceravel.github.io/demeter/. - XRD data - can be opened with a text file editor or Microsoft Excel.
Supercapacitors, Electrochemistry, Metal-Organic Frameworks, Structure-Property Investigations
Publication Reference: https://doi.org/10.1039/d1ta04026jhttps://www.repository.cam.ac.uk/handle/1810/324669
• Oppenheimer Studentship, School of the Physical Sciences, University of Cambridge. • Royal Society University Research Fellowship (UF100278), Royal Society. • UK Materials and Molecular Modelling Hub for computational resources, which is partially funded by EPSRC (EP/P020194/1 and EP/T022213/1). • Royal Society PhD funding, Royal Society. • Winton Programme for the Physics of Sustainability, University of Cambridge. • BP Next Generation Fellowship, Yusuf Hamied Department of Chemistry, University of Cambridge. • UKRI Future Leaders Fellowship (MR/T043024/1), UK Research and Innovation.
Faraday Institution (via University Of Sheffield) (FIRG017 160768)
Innovate UK (104384)
European Commission Horizon 2020 (H2020) ERC (726380)
Isaac Newton Trust (13.21(c)/18.47(a))
This record's DOI: https://doi.org/10.17863/CAM.71950