Manipulating Color Emission in 2D Hybrid Perovskites by Fine Tuning Halide Segregation: A Transparent Green Emitter
dc.contributor.author | Zanetta, Andrea | |
dc.contributor.author | Andaji‐Garmaroudi, Zahra | |
dc.contributor.author | Pirota, Valentina | |
dc.contributor.author | Pica, Giovanni | |
dc.contributor.author | Kosasih, Felix Utama | |
dc.contributor.author | Gouda, Laxman | |
dc.contributor.author | Frohna, Kyle | |
dc.contributor.author | Ducati, Caterina | |
dc.contributor.author | Doria, Filippo | |
dc.contributor.author | Stranks, Samuel D. | |
dc.contributor.author | Grancini, Giulia | |
dc.date.accessioned | 2021-10-18T08:52:15Z | |
dc.date.available | 2021-10-18T08:52:15Z | |
dc.date.issued | 2021-10-17 | |
dc.date.submitted | 2021-07-31 | |
dc.identifier.issn | 0935-9648 | |
dc.identifier.issn | 1521-4095 | |
dc.identifier.other | adma202105942 | |
dc.identifier.uri | https://www.repository.cam.ac.uk/handle/1810/329567 | |
dc.description | Funder: Engineering and Physical Sciences Research Council; Id: http://dx.doi.org/10.13039/501100000266 | |
dc.description | Funder: Cambridge Trust Scholarship | |
dc.description | Funder: Robert Gardiner Scholarship | |
dc.description | Funder: Royal Society; Id: http://dx.doi.org/10.13039/501100000288 | |
dc.description.abstract | Abstract: Halide perovskite materials offer an ideal playground for easily tuning their color and, accordingly, the spectral range of their emitted light. In contrast to common procedures, this work demonstrates that halide substitution in Ruddlesden–Popper perovskites not only progressively modulates the bandgap, but it can also be a powerful tool to control the nanoscale phase segregation—by adjusting the halide ratio and therefore the spatial distribution of recombination centers. As a result, thin films of chloride‐rich perovskite are engineered—which appear transparent to the human eye—with controlled tunable emission in the green. This is due to a rational halide substitution with iodide or bromide leading to a spatial distribution of phases where the minor component is responsible for the tunable emission, as identified by combined hyperspectral photoluminescence imaging and elemental mapping. This work paves the way for the next generation of highly tunable transparent emissive materials, which can be used as light‐emitting pixels in advanced and low‐cost optoelectronics. | |
dc.language | en | |
dc.subject | Research Article | |
dc.subject | Research Articles | |
dc.subject | 2D perovskites | |
dc.subject | halide mixtures | |
dc.subject | light emission | |
dc.subject | segregation | |
dc.subject | transparent light‐emitting devices | |
dc.subject | tunability | |
dc.title | Manipulating Color Emission in 2D Hybrid Perovskites by Fine Tuning Halide Segregation: A Transparent Green Emitter | |
dc.type | Article | |
dc.date.updated | 2021-10-18T08:52:14Z | |
prism.publicationName | Advanced Materials | |
dc.identifier.doi | 10.17863/CAM.77015 | |
rioxxterms.versionofrecord | 10.1002/adma.202105942 | |
rioxxterms.version | AO | |
rioxxterms.version | VoR | |
rioxxterms.licenseref.uri | http://creativecommons.org/licenses/by-nc/4.0/ | |
dc.contributor.orcid | Grancini, Giulia [0000-0001-8704-4222] | |
pubs.funder-project-id | European Research Council (802862, Fondazione CRUI) | |
pubs.funder-project-id | FARE Ricerca In Italia (R18ENKMTA3) | |
pubs.funder-project-id | European Research Council (756962) | |
pubs.funder-project-id | EPSRC (EP/R023980/1) | |
pubs.funder-project-id | Tata Group (UF150033) |
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