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Formation of a unique 'unsupported' hydridic stannate(II).

Accepted version
Peer-reviewed

Repository URI

https://www.repository.cam.ac.uk/handle/1810/256342

Repository DOI

https://doi.org/10.17863/CAM.285
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Accepted version (345.91 KB)

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Article

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Abstract

The reaction of the amido-stannate LiSn(NMe2)3 with the phosphine-borane (t)Bu2PHBH3 gives the Sn(II) hydride [(Me2NH)2Li{BH3P((t)Bu)2}2Sn(H)]; the first example of a hydridic stannate(ii) that is not supported by transition metal or ligand bonding.

Description

Keywords

3402 Inorganic Chemistry, 34 Chemical Sciences

Journal Title

Chem Commun (Camb)

Conference Name

Journal ISSN

1359-7345
1364-548X

Volume Title

52

Publisher

Royal Society of Chemistry (RSC)

Publisher DOI

https://doi.org/10.1039/c6cc01885h

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Sponsorship
Engineering and Physical Sciences Research Council (EP/K039520/1)

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Is supplemented by:
https://doi.org/10.1039/c6cc01885h

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Scholarly Works - Chemistry
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